Search results for "Chemical reactor"

Numerical study of the growth conditions in an MOCVD reactor: application to the epitaxial growth of HgTe

2002

Abstract In order to analyse the epitaxial growth by metalorganic chemical vapour deposition (MOCVD) of mercury telluride, HgTe, a 2D numerical model has been developed to simulate the gas flow in a horizontal MOCVD reactor. This model takes into account the Navier–Stokes equations coupled with the heat transfer and mass transport of chemical species. For the mathematical resolution of the governing equations a commercial solver, which can be run in a conventional personal computer, has been used. The study carried out presents a discussion about the dominant growth regime in a MOCVD growth as a function of different parameters: substrate temperature, total flow, partial pressure of precurs…

ELECTROCHEMICAL MICROREACTORS FOR THE ABATEMENT OF ORGANIC POLLUTANTS IN WATER SOLUTION

2015

Electrochemical methods can offer new sustainable routes for the abatement of organic pollutants resistant to biological processes. These methods use a clean reagent, the electron, and very mild operative conditions (ambient temperature and atmospheric pressure) with limited operative costs. However, electrochemical processes present some important disadvantages when performed in conventional reactors. In particular, to achieve reasonable cell voltages when the medium has not an adequate conductivity, one needs adding to the system a supporting electrolyte. This is certainly a main obstacle for a wide application of electrochemical tools. Indeed, adding chemicals is often a problematic issu…

Simplified Modeling of Radiant Fields in Heterogeneous Photoreactors. 1. Case of Zero Reflectance

1997

A strongly simplified model is proposed for the estimation of the radiant flow field, and related quantities such as the local volumetric rate of energy absorption, in heterogeneous photoreactors. The model is based on the assumption that a photon carrying energy greater than that of the catalyst band gap, when interacting with a catalyst particle, is invariably absorbed. The model equations allow, for simple geometries, analytical integral solutions to be obtained. These have the advantage of giving an immediate grasp on how the main physical parameters affect the radiation field:  an important feature especially for engineering purposes. The case developed here is that of a plane slab, fo…

Photoelectrochemical monitoring of rouging and de-rouging process on AISI 316L for chemical reactors

2016

The food and fine-chemical industry has for a long time been troubled by red brown to dark violet deposits in distillation columns, storage vessels and distribution systems for purified water and clean steam. Owing to the visual appearance of those deposits, the phenomena was referred as rouge. Although formation of rouge, i.e. rouging, is a commonly known phenomenon in stainless steel systems, the basic mechanism is still not fully understood. The phenomenon causes precipitation of iron as fine red-brown ferric oxide or hydroxide particles. Moreover adherent discoloration of the stainless steel surface is often observed in conjunction with the loosely adhered rouge particles. The affected …

Monitoring of Rouging and De-Rouging of Stainless Steel for Chemical Reactors by Photoelectrochemical and Impedance Measurements

2016

The food and fine-chemical industry has for a long time been troubled by red brown to dark violet deposits in distillation columns, storage vessels and distribution systems for purified water and clean steam. Owing to the visual appearance of those deposits, the phenomena was referred as rouge. Although formation of rouge, i.e. rouging, is a commonly known phenomenon in stainless steel systems, the basic mechanism is still not fully understood. The phenomenon causes precipitation of iron as fine red-brown ferric oxide or hydroxide particles. Moreover adherent discoloration of the stainless steel surface is often observed in conjunction with the loosely adhered rouge particles. The affected …

Quasi-isoactinic reactor for photocatalytic kinetics studies

2007

Photochemical reactors characterized by almost uniform values of the local volumetric rate of photon absorption (LVRPA), i.e., quasi-isoactinic photoreactors, are particularly suitable for assessing the influence of radiant field intensity in kinetic studies. In this work, Monte Carlo simulations have been performed to obtain LVRPA values in a flat photoreactor irradiated on both sides. This configuration appears to be particularly suitable for obtaining quasi-isoactinic conditions. The influence of catalyst albedo and scattering phase function is assessed, and the conditions for obtaining iso-actinicity are discussed. Finally, these conditions are related to an easy-to-measure parameter, n…

1978

A reaction vessel automatically controlled by magnetic valves is described which allows kinetic measurements of reactions with half lives t1/2≥2s by gravimetric determination of the conversion. Thus, it covers the gap between the flow tube and the conventional reaction vessel. The influence of mixing time and filling time on the molecular weight distribution of an anionically prepared polymer is discussed.